中大研發(fā)新型電解槽有效促進二氧化碳回收 助實踐碳中和目標(biāo)
指南者留學(xué)
2022-07-28 15:38:35
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<div class="ace-line ace-line old-record-id-doxcnOqsmsEK0sMe2QzW2NQWYAd" style="text-align: justify;"><span class="h6">王教授研究團隊研發(fā)的酸性二氧化碳電解槽,能有效回收及轉(zhuǎn)化二氧化碳,為化工制造業(yè)實踐碳中和目標(biāo)提供新路向。</span></div>
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<div class="ace-line ace-line old-record-id-doxcnSuwco0i8msIA65nCrQQiGc" style="text-align: justify;"><span class="p">香港中文大學(xué)(中大)化學(xué)系助理教授<strong>王瑩教授</strong>領(lǐng)導(dǎo)的研究團隊最近研發(fā)了一種新型電化學(xué)系統(tǒng)—酸性二氧化碳電解槽,可利用再生能源將二氧化碳(CO((2)))與水(H((2))O)轉(zhuǎn)化成商用化工原材料,轉(zhuǎn)化效率高達60%,有助化工產(chǎn)業(yè)實現(xiàn)低碳轉(zhuǎn)型。 研究成果最近已刊登在著名科學(xué)期刊《自然催化》上。</span></div>
<div class="ace-line ace-line old-record-id-doxcnIOgYwSkc6eyyA7o0pRJJVw" style="text-align: justify;"><span class="p"> </span></div>
<div class="ace-line ace-line old-record-id-doxcnEeMAumuWSGgokZNuUF8Vrh" style="text-align: justify;"><span class="p"><strong>目前CO</strong>((2))<strong>電解槽技術(shù)的碳利用效率甚低</strong></span></div>
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<div class="ace-line ace-line old-record-id-doxcnaU02gMyOiQI6yr0x3v66tb" style="text-align: justify;"><span class="p">要減緩全球暖化的影響,除了減少溫室氣體排放外,降低大氣中的CO((2))含量同樣重要。 全球有近八成的CO((2))排放量來自燃燒化石燃料,而日常生活中經(jīng)常接觸到的物品如化妝品、洗滌劑和塑膠等,皆由燃燒化石燃料后經(jīng)化學(xué)合成得來的副產(chǎn)品。 因此,發(fā)展碳捕獲和轉(zhuǎn)化技術(shù),如電化學(xué)CO((2))還原反應(yīng)(CO((2)) reduction reaction,CO((2))RR),將燃燒化石燃料排放出來的CO((2))回收轉(zhuǎn)化為生產(chǎn)這些化工制品的原材料,被視為是減少對化石燃料依賴的重要方法之一。</span></div>
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<div class="ace-line ace-line old-record-id-doxcnIw8ICo0qCwOOGUaqln5S9b" style="text-align: justify;"><span class="p">目前電化學(xué)CO((2))RR多在堿性條件下進行,轉(zhuǎn)化過程中有逾85%的CO((2))會被電解液消耗并產(chǎn)生碳酸鹽,大量流失可使用的CO((2))。 故化工業(yè)界往往需要利用額外能源及成本回收CO((2))并將其轉(zhuǎn)化,碳利用率低至25%。</span></div>
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<div class="ace-line ace-line old-record-id-doxcncuAc6s2K00kQGkFudh805c" style="text-align: justify;"><span class="p"><strong>新型酸性CO</strong>((2))<strong>電解槽加入鈀銅催化劑提升碳利用率</strong></span></div>
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<div class="ace-line ace-line old-record-id-doxcnayWee6GsuAyOQTIKGtGh9e" style="text-align: justify;"><span class="p">為提高碳利用效率,王教授與多倫多大學(xué)電子與計算機工程系團隊合作,研發(fā)一種新型酸性CO((2))電解槽,有效抑制碳酸鹽的形成,減少CO((2)) 在轉(zhuǎn)化過程中流失。 團隊更加入鈀銅催化劑(Palladium-Copper catalyst,Pd-Cu catalyst),以抑制酸性環(huán)境下產(chǎn)氫反應(yīng)(hydrogen evolution reaction,HER)所帶來的競爭反應(yīng),將碳利用率提升,令更多CO((2))轉(zhuǎn)換成重要化工原料,如乙烯(Ethylene)。 在電流密度為500 mA/cm((2)) 的條件下,新型酸性CO((2))電解槽系統(tǒng)能有效將CO((2))利用率提升至60%。</span></div>
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<div class="ace-line ace-line old-record-id-doxcn4O0k4UoAMq0gMtrG2ajW21" style="text-align: justify;"><span class="p">王教授說:「此項目能夠打破當(dāng)前堿性CO((2))RR電解槽碳利用率的上限。 我們正在努力擴大原型制作,希望將技術(shù)產(chǎn)業(yè)化,為發(fā)展環(huán)??萍技熬G色經(jīng)濟轉(zhuǎn)型出一分力。”</span></div>
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<div class="ace-line ace-line old-record-id-doxcn6SsWuoS6mwgyK4XBZQ23Kd" style="text-align: justify;"><span class="p">研究論文全文:<a href="https://www.nature.com/articles/s41929-022-00788-1" target="_blank" rel="noopener">https://www.nature.com/articles/s41929-022-00788-1</a></span></div>
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<div class="ace-line ace-line old-record-id-doxcn8mO8k22YK2kCAQW9GVH4no" style="text-align: justify;"><span class="p"><strong>關(guān)于王瑩教授</strong></span></div>
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<div class="ace-line ace-line old-record-id-doxcnmqke2WgWIcmgsvQWPY3cJd" style="text-align: justify;"><span class="p">王教授于2019年加入中大。 她的研究小組一直專注于研究電催化的理解和裝置工程。 是次研究獲得研究資助委員會下的杰出青年學(xué)者計劃支持。</span></div>
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